Valence band behaviour of zirconium oxide, Photoelectron and Auger spectroscopy study

Z.Azdad Möri ,L. Mosera, R. Steinera and E. Meyer

Published results

Research Contribution: Electronic Structure of Zirconium Oxide

Valence Band Behavior

  • The position of oxygen (O2p) bands remains stable despite changes in oxygen concentration
  • This stability provides a reliable reference point for spectroscopic measurements

Oxidation Process Insights

  • Tracked zirconium oxidation using advanced spectroscopic techniques
  • Observed how oxygen content affects electronic structure
  • Identified changes in metallic and oxide-related electron transitions

Innovative Charge Correction Method

  • Developed a new XPS charge correction technique using Auger transitions
  • Enabled more accurate binding energy measurements
  • Validated method by comparison with traditional techniques

Methodology

  • X-ray Photoelectron Spectroscopy (XPS)
  • Ultraviolet Photoelectron Spectroscopy (UPS)
  • Auger Electron Spectroscopy
  • Magnetron sputtering for film preparation

Significance

  • Improved understanding of zirconium oxide's electronic structure
  • Better characterization techniques for oxide materials
  • Potential in advanced electronics and sensor technology

Potential Future Applications

  • Solid oxide fuel cells
  • Gas sensors
  • Protective coatings
  • Semiconductor device innovation

Full Publication

Master Thesis Work Certificate

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